There are a number of ways to do this, butusing Group Policy is likely to be the best.
1. Open the Default Domain Policy MMC snap-in.
2. Expand Computer Configuration / Administrative Templates / System.
3. Double-click Run these programs at user logon.
4. Enable the policy.
5. Press Show to modify the list.
NOTE: This policy configures HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\policies\Explorer\Run.
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